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The Dewar–Chatt–Duncanson model is a model in organometallic chemistry which explains the type of chemical bonding between an alkene and a metal (pi-complex) in certain organometallic compounds. The model is named after Michael J. S. Dewar,〔Dewar, M. Bull. Soc. Chim. Fr. 1951, 1 8 , C79〕 Joseph Chatt and L. A. Duncanson.〔''Olefin co-ordination compounds. Part III. Infra-red spectra and structure: attempted preparation of acetylene complexes'' J. Chatt and L. A. Duncanson, J. Chem. Soc., 1953, 2939 〕〔''Directing effects in inorganic substitution reactions. Part I. A hypothesis to explain the trans-effect'' J. Chatt, L. A. Duncanson, L. M. Venanzi, J. Chem. Soc., 1955, 4456-4460 〕 The pi-acid alkene donates electron density into a metal sp3 orbital from a π-symmetry bonding orbital between the carbon atoms. The metal donates electrons back from (a different) filled d-orbital into the empty π * antibonding orbital. Both of these effects tend to reduce the carbon-carbon bond order, leading to an elongated C-C distance and a lowering of its vibrational frequency. In Zeise's salt K The interaction also causes carbon atoms to "rehybridise" from sp2 towards sp3, which is indicated by the bending of the hydrogen atoms on the ethylene back away from the metal.〔.〕 In silico calculations show that 75% of the binding energy is derived from the forward donation and 25% from backdonation.〔Herrmann/Brauer: ''Synthetic Methods of Organometallic and Inorganic Chemistry'' Georg Thieme, Stuttgart, 1996〕 This model is a specific manifestation of the more general pi backbonding model. ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Dewar–Chatt–Duncanson model」の詳細全文を読む スポンサード リンク
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